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Colour wheel

The wheel orders hues so opposites are complementary. Primaries (red, yellow, blue) can't be mixed from other colours; secondaries (orange, green, violet) are equal mixes of two primaries; tertiaries sit between them.

Complementary colours

Opposites on the wheel. Mixed together they neutralise toward grey — useful for muting overly bright passages and for painting believable shadows. Placed side-by-side they intensify each other.

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Tip: instead of black, mix a colour's complement into it for a more lifelike, chromatic shadow.

Other schemes

  • Analogous — 3 neighbours on the wheel. Harmonious, calm (e.g. yellow, yellow-orange, orange).
  • Triadic — 3 colours equally spaced. Vivid, balanced (e.g. red, yellow, blue).
  • Split-complement — a colour plus the two neighbours of its complement. Strong contrast, less tension than a direct complement.
  • Limited palette — 3–6 paints chosen for unity. Forces mixing skill and produces cohesive paintings.

Temperature

Every hue has warm and cool versions. A "warm" red leans orange (Cadmium Red, PR108); a "cool" red leans pink/violet (Quinacridone Magenta, PR122). Choosing the right bias controls how a mix shifts:

  • • Warm + warm → bright secondary (warm red + warm yellow = vivid orange).
  • • Warm + cool → muted secondary (warm red + cool yellow = duller orange — they fight each other).
  • • Two cool primaries → cleanest violets/greens (cool red + cool blue = clean violet).

Value structure

Value (lightness) does more work than hue. A painting with strong value structure reads from across the room. Squint at your reference — what you still see is the value pattern.

Aim for a clear "dark / mid / light" plan before colour. Reserve your darkest darks and lightest lights for focal points.

Opacity & transparency

  • Opaque (Cadmiums, Titanium White, most earths) — covers what's underneath. Best for solid forms and corrections.
  • Semi-transparent — partial coverage; useful for scumbling.
  • Transparent (Phthalos, Quinacridones, Dioxazine Violet) — light passes through. Best for glazing and luminous shadows.
  • Staining — bonds aggressively; hard to lift. Phthalos and Quinacridones stain.

In watercolour: transparency = luminosity. In oil/acrylic: layer opaque over transparent darks for depth ("fat over lean" in oils).

Pigment codes

The Colour Index uses letter+number codes that identify the actual pigment, regardless of marketing name. P = pigment, then a letter for hue family (B blue, R red, Y yellow, G green, V violet, W white, Bk black, Br brown), then a number. Two tubes with the same code behave the same way, even from different brands.

CodeCommon nameTemperatureOpacityLightfastness
PB29Ultramarine BlueWarm blueSemi-transparentExcellent
PB15Phthalo BlueCool blueTransparent (staining)Excellent
PG7Phthalo GreenCool greenTransparent (staining)Excellent
PG36Phthalo Green YSWarm greenTransparentExcellent
PY35Cadmium YellowCool yellowOpaqueExcellent
PY3Hansa Yellow LightCool yellowSemi-transparentGood
PY74Hansa Yellow MediumWarm yellowSemi-transparentGood
PY42Yellow OchreWarm earthOpaqueExcellent
PR108Cadmium RedWarm redOpaqueExcellent
PR254Pyrrole RedWarm redSemi-opaqueExcellent
PR122Quinacridone MagentaCool redTransparent (staining)Excellent
PR101Burnt Sienna / Indian RedWarm earthSemi-opaqueExcellent
PR206Quinacridone Burnt OrangeWarm earthTransparentExcellent
PBr7Raw / Burnt UmberCool earthSemi-transparentExcellent
PV19Quinacridone Rose/VioletCoolTransparent (staining)Excellent
PV23Dioxazine VioletCoolTransparentGood
PW6Titanium WhiteCool whiteOpaqueExcellent
PW4Zinc WhiteCool, softSemi-transparentExcellent
PBk7Lamp / Carbon BlackCool blackOpaqueExcellent
PBk9Ivory / Bone BlackWarm blackSemi-opaqueExcellent

Tips by medium

Oil

Slow drying — let layers tack up before reworking. "Fat over lean": more oil/medium in upper layers to avoid cracking. Wipe brushes between mixes; don't pollute your whites.

Acrylic

Dries 1-2 values darker than wet. Work fast or use a retarder. Glazing medium turns any opaque into a transparent glaze. Phthalos stain — keep a dedicated brush.

Watercolour

Plan lights first — you can't add white back easily. Wet-on-wet for soft edges, wet-on-dry for crisp ones. Lift mistakes with a damp clean brush before they dry.

Gouache

Like opaque watercolour. Rewets even after drying — handy for blending, risky for layering. Slightly dulls when dry. Excellent for flat colour and illustration.

Ink

Permanent once dry. Build value with dilution or hatching. Combine with watercolour for line+wash.

Glossary

Hue
The colour family — red, blue, etc.
Value
How light or dark a colour is.
Chroma / Saturation
How pure or intense a colour is (vs. neutral grey).
Tint
Hue mixed with white — lighter, often less chromatic.
Shade
Hue mixed with black — darker, often muddier.
Tone
Hue mixed with grey — softer, more sophisticated.
Gamut
The total range of colours a palette can mix.
Glaze
A thin transparent layer over a dry layer; shifts the colour underneath.
Scumble
A thin broken layer of opaque/semi-opaque paint over a dry layer.
Local colour
The 'true' colour of an object before light/shadow.
Lightfastness
Resistance to fading from light exposure (I = excellent).
ΔE (Delta E)
Perceptual distance between two colours. Under ~2 is indistinguishable.